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⚡ CHEAT SHEET

Ch.4: Pesticide Formulations

High-yield exam facts: What a formulation is; Reading the label suffix; Table 4.1 suffixes; Solubility and mixtures; Formulation types — defining traits & key pros/cons; Adjuvants; Choosing a formulation; Key Vocabulary

National CORE · 2025 Third Edition · Ch.4

1. What a formulation is

  • A formulation = an active ingredient (a.i.) combined with other ingredients. For most purposes, "formulation" ≈ "product."
  • The same a.i. is sold in many forms to meet different pest-control needs (e.g., glyphosate has terrestrial and aquatic formulations). Using the wrong form in the wrong place = poor control, and off-label site use is illegal.
  • Active ingredients have a direct effect on the pest. Concentrated a.i. can be extremely toxic, hard to mix with water, unstable, or unsafe to handle.
  • Other ingredients don't affect the pest directly but make the product more useful, effective, and safer to handle (help it dissolve, keep it from settling, help it stick, extend shelf life, improve pouring).
  • Synergist = a chemical that boosts an a.i.'s activity; alone it has little or no activity against the pest.
  • ⚠️ Other ingredients are not necessarily harmless — some can be more hazardous than the a.i. The signal word is based on the TOTAL formulation, not just the a.i. Hazard info is in the SDS.

2. Reading the label suffix

  • A suffix on the brand/trade name signals the formulation (Table 4.1).
  • Solid formulations: suffix number = % a.i. by weight → BugGone 20WP = wettable powder, 20% a.i. by weight.
  • Liquid formulations: suffix number = pounds a.i. per gallon → WeedXterminator 3.3EC = emulsifiable concentrate, 3.3 lb a.i./gal.
  • No suffix? Find it in the Product Information section of the label.

3. Table 4.1 suffixes

Suffix
Formulation
D
Dust
E / EC
Emulsifiable concentrate
G
Granules
L / F (SC)
Liquid flowable (suspension concentrate)
M
Microencapsulated
P / PS
Pellet
SP
Soluble powder
ULV
Ultra low volume
WDG (DF)
Water-dispersible granule (dry flowable)
WP
Wettable powder

4. Solubility and mixtures

  • Solubility = ability of a substance to dissolve in a solvent (usually water). Salt = soluble; oil = insoluble.
  • True solution — can't be separated by filtration; doesn't settle out or need shaking (e.g., SP in water).
  • Suspension — solid particles that don't dissolve, dispersed in liquid; needs agitation or particles settle/float; looks cloudy.
  • Emulsion — a special suspension: droplets of one liquid in another; looks cloudy/milky. An emulsifier keeps it from separating (oil rising to the top).

5. Formulation types — defining traits & key pros/cons

  • Emulsifiable Concentrate (EC) — a.i. insoluble in water, dissolved in a petroleum solvent (solvent odor). ✅ easy to handle/pour, little agitation, not abrasive. ❌ easily skin-absorbed, corrosive, flammable, can deteriorate rubber/plastic. Keep off skin — high a.i. concentration.
  • Ultra Low Volume (ULV) — almost 100% a.i., very fine droplets at high pressure. ❌ high drift, high dermal and inhalation risk. Best outdoors (mosquito, forestry).
  • Wettable Powder (WP) — dry solid that doesn't dissolve; diluted with water → suspension. ✅ less skin/eye absorption and less plant harm than ECs. ❌ inhalation hazard while mixing, must be weighed, abrasive, clogs nozzles, needs constant agitation.
  • Soluble Powder (SP) — looks like WP but dissolves into a true solution (no extra agitation). Has all WP advantages with only one disadvantage: inhalation hazard during mixing.
  • Water-Dispersible Granule (WDG / DF) — WP made into granules: pours easier, suspends better, less inhalation risk; still a suspension needing agitation; granules break into fine powder in water.
  • Liquid Flowable (L / F) — thick liquid suspension. ✅ low inhalation risk, seldom clogs nozzles. ❌ shake before mixing, moderate agitation, abrasive, visible residue.
  • Microencapsulated (M / ME) — a.i. in tiny plastic-coated capsules → slow release, effective longer. ❌ needs constant agitation; hazard to bees (carry capsules with pollen to the hive).
  • Dust (D) — always used dry; a.i. + fine carrier (talc, chalk, clay). Good where spray moisture would damage. ❌ drifts easily, poor adherence, high inhalation risk.
  • Granule (G) — a.i. on clay/porous material; nearly always treats soil; slow release (may need soil moisture).
  • Pellet (P) — like granules but uniform in size/shape (granules vary); spot applications; ❌ bird hazard (mistaken for food).
  • Bait — a.i. + food/attractant; a.i. usually < 5%. ✅ whole area needn't be covered. Rodent baits often require tamper-proof bait stations; remove old bait so it doesn't feed pests.
  • Water-soluble bag (WSB) — premeasured, lowers exposure to concentrated a.i. Never puncture or break it open — add whole to water.

6. Adjuvants

  • Adjuvant (additive) = material added to the tank mix to aid/modify the formulation's action or the mixture. Most common for foliar applications.
  • Surfactants (wetting agents, spreader-stickers) — reduce surface tension, increase spreading on leaves (like soap in water); the ones applicators add most.
  • Drift reduction (thickening) agents — help reduce but not eliminate drift.
  • Compatibility agents — allow effective mixing of two or more pesticides.
  • Add carefully: some need a specific mixing order; too little/much can ruin the mix or injure plants.

7. Choosing a formulation

  1. #1 concern: the product is labeled for your site/plant/crop.
  2. Signal word — between two that work, choose the less toxic.
  3. Applicator safety (inhalation vs. skin) — have the right PPE.
  4. Environmental safety — caution with drift-prone/volatile products; some are more toxic to aquatic life.
  5. Pest biology, surface (staining, plastic, foliage damage), equipment (abrasive/corrosive).
  6. Cost matters, but safety and pest management come first.

Key Vocabulary

Term
Meaning (per Ch.4)
Formulation
A.i. combined with other ingredients (≈ product)
Carrier
The liquid or solid that dilutes/carries the a.i.
Concentration
Amount of a.i. in the product
Solubility / Soluble
Ability to dissolve / able to dissolve in a solvent
Solvent
The liquid a substance dissolves into
Solution
A mixture that can't be filtered apart and needs no shaking
Suspension
Undissolved solid particles dispersed in liquid; needs agitation
Emulsion
Droplets of one liquid suspended in another
Emulsifier
Keeps an emulsion from separating
Synergist
Boosts an a.i.'s activity (little activity alone)
Adjuvant
Additive to a tank mix that aids/modifies the mixture
Diluted
Made less concentrated by adding a carrier
Spray drift
Off-target movement of spray droplets
Volatile
Prone to turning into a gas/vapor
Phytotoxic
Capable of injuring plants
Vertebrate
Animal with a backbone (e.g., rodents, birds targeted by baits)

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